2-(4-Bromophenyl)-N-(5-methylpyridin-2-yl)acetamide
نویسندگان
چکیده
The asymmetric unit of the title compound, C(14)H(13)BrN(2)O, consists of two mol-ecules; the dihedral angles between the pyridine and benzene rings are 87.99 (9) and 84.28 (9)°. An intra-molecular C-H⋯O hydrogen bond generates an S(6) ring in each mol-ecule. In the crystal, mol-ecules are linked via N-H⋯N and C-H⋯O hydrogen bonds into a three-dimensional network. The crystal structure also features weak π-π stacking inter-actrions between the benzene rings [centroid-to-centroid distance = 3.6829 (12) Å].
منابع مشابه
2-(4,6-Dimethylpyrimidin-2-ylsulfanyl)-N-(4-methylpyridin-2-yl)acetamide
The non-H atoms of the title mol-ecule, C(14)H(16)N(4)OS, are coplanar, with an r.m.s. deviation of 0.039 Å. The dihedral angle between the two aromatic rings is 2.4 (2)°. An intra-molecular C-H⋯O hydrogen bond is observed. The mol-ecules exist as N-H⋯N hydrogen-bonded centrosymmetric dimers.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012